学術論文(審査付き)

 

(2010)

(119) Hideto Tsuji, Satomi Yamamoto, Ayaka Okumura, Yu Sugiura; Hetero-Stereocomplexation between Biodegradable and Optically Active Polyesters as a Versatile Preparation Method for Biodegradable Materials, Biomacromolecules, in press.

[Table of Contents grafic for Biomacromolecules, in press]

(118) Hideto Tsuji, Mariko Sawada; Accelerated Crystallization of Poly(L-lactide) by Physical Aging, Journal of Applied Polymer Science, in press.

 

(2009)

(117) Hideto Tsuji, Ayaka Okumura; Stereocomplex Formation between Enantiomeric Substituted Poly(lactide)s: Blends of Poly[(S)-2-hydroxybutyrate] and Poly[(R)-2-hydroxybutyrate], Macromolecules (Communication), Vol. 42, No. 19, 7263-7266 (2009).

[Table of Contents grafic for Macromolecules (Communication), Vol. 42, No. 19, 7263-7266 (2009)]

(116) Hideto Tsuji, Mariko Sawada, Leevameng Bouapao; Biodegradable Polyesters as Crystallization-Accelerating Agents of Poly(L-lactide), ACS Appl. Mater. Interfaces, Vol.1, No. 8, pp. 1719-1730 (2009).

[Table of Contents grafic for ACS Appl. Mater. Interfaces, Vol.1, No. 8, pp. 1719-1730 (2009)]

(115) Leevameng Bouapao, Hideto Tsuji, Kohji Tashiro, Jianming Zhang, Makoto Hanesaka; Crystallization, Spherulite Growth, and Structure of Blends of Crystalline and Amorphous Poly(lactide)s, Polymer, Vol. 50, No. 16, pp. 4007-4017 (2009).

(114) Leevameng Bouapao, Hideto Tsuji; Stereocomplex Crystallization and Spherulite Growth of Low-Molecular-Weight Poly(L-lactide) and Poly(D-lactide) from the Melt, Macromolecular Chemistry and Physics, Vol. 210, No.12, pp. 993-1002 (2009).

(Leevameng Bouapao, Hideto Tsuji, Macromolecular Chemistry and Physics, Vol. 210, No. 12 (2009), cover picture)

(113) Swapan Kumar Saha, Hideto Tsuji; Enhanced Crystallization of Poly(L-lactide-co-e-caprolactone) in the Presence of Water, Journal of Applied Polymer Science, Vol. 112, No. 2, pp. 715-720 (2009).

 

(2008)

(112) Hideto Tsuji, Kohji Tashiro, Leevameng Bouapao, Junichi Narita; Poly(glycolide) as Biodegradable Nucleating Agent of Poly(L-lactide), Macromolecular Materials and Engineering (Communication), Vol. 293, No. 12, pp.947-951 (2008).

(111) Hideto Tsuji, Yoshiko Yamamura, Tomoyuki Ono, Takashi Saeki, Hiroyuki Daimon, Koichi Fujie; Hydrolytic Degradation and Monomer Recovery of Poly(butylene succinate) and Poly(butylene succinate/adipate) in the Melt, Macromolecular Reaction Engineering, Vol. 2, No. 6, pp. 522-528 (2008).

(110) Hideto Tsuji, Hiroshi Matsuoka, Shinichi Itsuno; Synthesis, Physical Properties, and Crystallization of Optically Active Poly(L-phenyllactic acid) and Poly(L-phenyllactic acid-co-L-lactic acid), Journal of Applied Polymer Science, Vol. 110, No. 6, pp. 3954-3962 (2008).

(109) Hideto Tsuji, Takashi Saeki, Takayuki Tsukegi, Hiroyuki Daimon, Koichi Fujie; Comparative Study on Hydrolytic Degradation and Monomer Formation of Poly(L-lactic acid) in the Solid and in the Melt, Polymer Degradation and Stability, Vol. 93, No. 10, pp.1956-1963 (2008).

(108) Hideto Tsuji, Hiroshi Matsuoka; Stereoselective Interaction between Isotactic and Optically Active Poly(lactic acid) and Phenyl-Substituted Poly(lactic acid), Macromolecular Rapid Communications, Vol. 29, No. 16, pp.1372−1377 (2008).

(107) Hideto Tsuji, Yu Sugiura, Yuzuru Sakamoto, Leevameng Bouapao,and Shinichi Itsuno; Crystallization Behavior of Linear 1-Arm and 2-Arm Poly(L-lactide)s: Effects of Coinitiators, Polymer, Vol. 49, No. 5, pp.1385-1397 (2008).

(106) Jianming Zhang, Kohji Tashiro, Hideto Tsuji, and Abraham J. Domb; Disorder-to-Order Phase Transition and Multiple Melting Behavior of Poly(L-lactide) Investigated by Simultaneous Measurements of WAXD and DSC, Macromolecules, Vol. 41, No. 4, pp. 1352-1357 (2008).

 

(2007)

(105) Hideto Tsuji, Misato Nishikawa, Yasushi Osanai, Shuichi Matsumura; New Strategy for Controlling Biodegradability of Biodegradable Polyesters by Enzyme-Catalyzed Surface Grafting, Macromolecular Rapid Communications, Vol. 28, No. 16, pp.1651-1656 (2007).

[Table of Contents grafic for Macromolecular Rapid Communications, Vol. 28, No. 16, pp.1651-1656 (2007)]

(104) Hideto Tsuji, Yoshio Kawashima, Hirofumi Takikawa, Saburo Tanaka; Poly(L-lactide) / Nano-Structured Carbon Composites: Conductivity, Thermal Properties, Crystallization, and Biodegradation, Polymer, Vol. 48, No. 14, pp.4213-4225 (2007).

(103) Hideto Tsuji, Yoshio Kawashima, Hirofumi Takikawa; Poly(L-lactide) / C60 Nanocomposites: Effects of C60 on Crystallization of Poly(L-lactide), Journal of Polymer Science, Part B: Polymer Physics, Vol. 45, No. 16, pp. 2167-2176 (2007).

(102) Hideto Tsuji, Misato Nishikawa, Yuzuru Sakamoto, Shinichi Itsuno; A Novel Preparation Method for Poly(L-lactide)-Based Block Copolymers: Extended Chain Crystallites as a Solid State Macro-Coinitiator, Biomacromolecules, Vol. 8, No. 5, pp. 1730-1738 (2007).

[Table of Contents grafic for Biomacromolecules, Vol. 8, No. 5, pp. 1730-1738 (2007)]

(101) Jianming Zhang, Kohji Tashiro, Hideto Tsuji, Abraham J. Domb; Investigation of Phase Transitional Behavior of Poly(L-lactide)/Poly(D-lactide) Blend Used to Prepare the Highly-Oriented Stereocomplex, Macromolecules, Vol. 40, No. 4, pp. 1049-1054 (2007).

(100) Muhammad Faisal, Takashi Saeki, Hideto Tsuji, Hiroyuki Daimon, Koichi Fujie; Depolymerization of Poly(L-lactic acid) under Hydrothermal Conditions, Asian Journal of Chemistry, Vol. 19, No. 3, pp.1714-1722 (2007).

(99) 高山 哲生,東藤 貢,辻 秀人,新川 和夫,PLLA/PCLの相構造と機械的特性に及ぼすP(LLA-CL)ブレンドの影響, 材料, Vol. 56, No. 3, pp. 211-216 (2007).

(98) Hideto Tsuji, Gen Horikawa, Shinichi Itsuno; Melt-Processed Biodegradable Polyester Blends of Poly(L-lactic acid) and Poly(e-caprolactone):Effects of Processing Conditions on Biodegradation, Journal of Applied Polymer Science, Vol. 104, No. 2, pp.831-841(2007).

(97) Hideto Tsuji, Gen Horikawa; Porous Biodegradable Polyester Blends of Poly(L-lactic acid) and Poly(e-caprolactone): Physical Properties, Morphology, and Biodegradation, Polymer International, Vol. 56, No. 2, pp. 258-266 (2007).

(96) Hideto Tsuji, Yuki Kidokoro, Masatsugu Mochizuki: Enzymatic Degradation of Poly(L-lactic acid) Fibers: Effects of Small Drawing, Journal of Applied Polymer Science, Vol. 103, No. 3, pp. 2064-2071(2007).

 

(2006)

(95) Jianming Zhang, Kohji Tashiro, Abraham J. Domb, Hideto Tsuji: Confirmation of Disorder Form of Poly(L-lactic acid) by the X-ray Fiber Pattern and Polarized IR/Raman Spectra Measured for Uniaxially-Oriented Samples, Macromolecular Symposia, Vol. 242, No.1, 274-278 (2006).

(94) Hideto Tsuji, Michihiko Nakano, Makoto Hashimoto, Kazunori Takashima, Shinji Katsura, Akira Mizuno; Electrospinning of Poly(lactic acid) Stereocomplex Nanofibers, Biomacromolecules, Vol. 7, No. 12, pp. 3316-3320 (2006).

[Table of Contents grafic for Biomacromolecules, Vol. 7, No. 12, pp. 3316-3320 (2006)]

(93) Jianming Zhang, Harumi Sato, Tsuyoshi Furukawa, Hideto Tsuji, Isao Noda, Yukihiro Ozaki; Crystallization Behaviors of Poly(3-hydroxybutyrate) and Poly(L-lactic acid) in Their Immiscible and Miscible Blends, Journal of Physical Chemistry B, Vol. 110, No. 48, pp. 24463-24471 (2006).

(92) Tetsuo Takayama, Mitsugu Todo, Hideto Tsuji, Kazuo Arakawa; Effect of LTI content on impact fracture property of PLA/PCL/LTI polymer blends, Journal of Materials Science, Vol. 41, No. 19, pp. 6501-6504 (2006).

(91) 高山 哲生,東藤 貢,新川 和夫,辻 秀人,PLA/PCLポリマーブレンドの相構造制御と破壊特性,日本複合材料学会誌,Vol. 32, No. 5, 218-225 (2006).

(90) Yongxin Duan, Jing Liu, Harumi Sato, Jianming Zhang, Hideto Tsuji, Yukihiro Ozaki, Shouke Yan; Molecular Weight Dependence of the Poly(L-lactide)/Poly(D-lactide) Stereocomplex at the Air-Water Interface, Biomacromolecules, Vol. 7, No. 10, pp. 2728 - 2735 (2006).

(89) Tetsuo Takayama, Mitsugu Todo, Hideto Tsuji, Kazuo Arakawa: Improvement of Fracture Properties of PLA/PCL Polymer Blends by Control of Phase Structures, Kobunshi Ronbunsyu, Vol. 63, No. 9, pp. 626-632 (2006). [In Japanese except for Abstract, Figures, and Tables (English)]

(88) Hideto Tsuji, Yuki Kidokoro, Masatsugu Mochizuki; Enzymatic Degradation of Biodegradable Polyester Composites oF Poly(L-lactic acid) and Poly(e-caprolactone), Macromolecular Materials and Engineering, Vol. 291, No. 10, pp.1245-1254 (2006).

(87) Hideto Tsuji, Hiroki Takai, Swapan Kumar Saha; Isothermal and Non-Isothermal Crystallization Behavior of Poly(L-lactic acid): Effects of Stereocomplex as Nucleating Agent, Polymer, Vol. 47, No. 11, pp. 3826-3837 (2006). [Erratum: p. 5430]

(86) Swapan Kumar Saha, Hideto Tsuji; Effects of Rapid Crystallization on Hydrolytic Degradation and Mechanical Properties of Poly(L-lactide-co-e-caprolactone), Reactive and Functional Polymers, Vol. 66, No. 11, pp. 1362-1372 (2006).

(85) Hideto Tsuji, Yoshihisa Echizen, Yoshiro Nishimura: Enzymatic Degradation of Poly(L-lactic acid): Effects of UV Irradiation, Journal of Polymers and the Environment, Vol. 14, No. 3, pp. 239-248 (2006).

(84) 高山 哲生,東藤 貢,新川 和夫,辻 秀人: PLA/PCL系ポリマーブレンドの破壊特性に及ぼす添加剤の影響, 日本機械学会論文集(A編), Vol. 72, No. 714, pp.173-178 (2006).

(83) Swapan Kumar Saha, Hideto Tsuji: Hydrolytic Degradation of Amorphous-Made Films of L-Lactide Copolymers with Glycolide and D-Lactide, Macromolecular Materials and Engineering, Vol. 291, No. 4, pp. 357-368 (2006).

(82) Swapan Kumar Saha, Hideto Tsuji: Effects of Molecular Weight and Small Amounts of D-lactide Units on Hydrolytic Degradation of Poly(L-lactic acid)s, Polymer Degradation and Stability, Vol. 91, No. 8, pp. 1665-1673 (2006).

(81) Hideto Tsuji, Hiroki Takai, Norio Fukuda, Hirofumi Takikawa: Non-Isothermal Crystallization Behavior of Poly(L-lactic acid) in the Presence of Various Additives, Macromolecular Materials and Engineering, Vol. 291, No. 4, pp. 325-335 (2006).

(80) Hideto Tsuji, Miyuki Ogiwara, Swapan Kumar Saha, Takuya Sakaki: Enzymatic, Alkaline, and Autocatalytic Degradation of Poly(L-lactic acid): Effects of Biaxial Orientation, Biomacromolecules, Vol. 7, No. 1, pp.380-387 (2006).

(79) Hideto Tsuji, Yoshihisa Echizen, Yoshiro Nishimura; Photodegradation of Biodegradable Polyesters, A Comprehensive Study on Poly(L-lactide) and Poly(e-caprolactone), Polymer Degradation and Stability, Vol. 91, No. 5, pp.1128-1137 (2006).

(78) Hideto Tsuji, Rumiko Okino, Hiroyuki Daimon, Koichi Fujie: Water Vapor Permeability of Poly(lactide)s: Effects of Molecular Characteristics and Crystallinity, Journal of Applied Polymer Science, Vol. 99, No. 5, pp. 2245-2252 (2006).

(Hideto Tsuji, Hiroki Takai, Norio Fukuda, Hirofumi Takikawa, Macromolecular Materials and Engineering, Vol.291, No.4 (2006), cover picture)

 

(2005)

(77) Hideto Tsuji, Yoshihisa Echizen, Swapan Kumar Saha, Yoshihisa Nishimura; Photodegradation of Poly(L-lactic acid): Effects of Photosensitizer, Macromolecular Materials and Engineering, Vol. 290, No. 12, 1192-1203 (2005).

(76) Jianming Zhang, Yongxin Duan, Harumi Sato, H. Tsuji, Isao Noda, Shouke Yan, Yukihiro Ozaki; Crystal Modifications and Thermal Behavior of Poly(L-lactic acid) Revealed by Infrared Spectroscopy; Macromolecules, Vol. 38, No. 19, pp.8012-8021 (2005).

(75) Hideto Tsuji, Yasufumi Tezuka, Swapan Kumar Saha, Masakazu Suzuki, Shinichi Itsuno: Spherulite Growth of L-lactide Copolymers: Effects of Tacticity and Comonomers, Polymer, Vol. 46, No.13, pp.4917-4927 (2005).

(74) Hideto Tsuji, Tomoyuki Ono, Takashi Saeki, Hiroyuki Daimon, Koichi Fujie: Hydrolytic Degradation of Poly(e-caprolactone) in the Melt, Polymer Degradation and Stability, Vol. 89, No. 2, pp. 336-343 (2005).

(73) Takashi Saeki, Takayuki Tsukegi, Hideto Tsuji, Hiroyuki Daimon, Koichi Fujie: Hydrolytic Degradation of Poly[(R)-3-hydroxybutyric acid] in the Melt, Polymer, Vol. 46, No. 7, pp. 2157-2162 (2005).

(72) Hideto Tsuji, Yasufumi Tezuka, Kazunobu Yamada: Alkaline and Enzymatic Degradation of L-Lactide Copolymers: 2. Crystallized Films of Poly(L-lactide-co-D-lactide) and Poly(L-lactide) with Similar Crystallinities, Journal of Polymer Science, Part B: Polymer Physics, Vol. 49, No. 3, pp.1064-1075 (2005).

(71) Jianming Zhang, Harumi Sato, Hideto Tsuji, Isao Noda, Yukihiro Ozaki: Infrared Spectroscopic Study of CH3・・・O=C Interaction during the Poly(L-lactide)/Poly(D-lactide) Stereocomplex Formation, Macromolecules, Vol. 38, No. 5, pp.1822-1828 (2005).

(70) Hideto Tsuji, Yasufumi Tezuka: Alkaline and Enzymatic Degradation of L-Lactide Copolymers:1. Amorphous-Made Films of L-Lactide Copolymers with D-Lactide, Glycolide, e-Caprolactone, Macromolecular Bioscience, Vol. 5, No. 2, pp.135-148 (2005).

(69) Jianming Zhang, Harumi Sato, Hideto Tsuji, Isao Noda, Yukihiro Ozaki: Differences in the CH3・・・O=C Interactions Among Poly(L-lactide), Poly(L-lactide)/Poly(D-lactide) Stereocomplex, and Poly(3-hydroxybutyrate) Studied by Infrared Spectroscopy, Journal of Molecular Structure, 735-736, pp. 249-257 (2005).

(68) Hideto Tsuji, Tatsuhiro Miyase, Yasufumi Tezuka, Swapan Kumar Saha: Physical Properties and Crystallization, and Spherulite Growth of Linear and 3-Arm Poly(L-lactide)s; Biomacromolecules, Vol. 6, No. 1, pp. 244-254 (2005).

(67) Norio Fukuda, Hideto Tsuji: Physical Properties and Enzymatic Hydrolysis of Poly(L-lactide)-TiO2 composites; Journal of Applied Polymer Science, Vol. 96, No. 1, pp.190-199 (2005).

 

(2004)

(66) Takashi Saeki, Takayuki Tsukegi, Hideto Tsuji, Hiroyuki Daimon, Koichi Fujie: Depolymerization of Poly(L-lactide) under Hydrothermal Conditions, Kobunshi Ronbunshu, Vol. 61, No. 11, pp. 561-566 (2004). [In Japanese except for Abstract, Figures, and Tables (English)]

(65) Jianming Zhang, Hideto Tsuji, Isao Noda, Yukihiro Ozaki: Weak Intermolecular Interaction during the Melt Crystallization of Poly(L-lactide) Investigated by Two-Dimensional Infrared Correlation Spectroscopy, Journal of Physical Chemistry B, Vol.108, No. 31, pp. 11514-11520 (2004).

(64) Jianming Zhang, Hideto Tsuji, Isao Noda, Yukihiro Ozaki: Structural Changes and Crystallization Dynamics of Poly(L-lactide) during the Cold-Crystallization Process Investigated by Infrared and Two-Dimensional Infrared Correlation Spectroscopy, Macromolecules, Vol. 37, No. 17, pp. 6433-6439 (2004).

(63) Hideto Tsuji, Yasufumi Tezuka: Stereocomplex Formation between Enantiomeric Poly(lactic acid)s. XII. Spherulite Growth of Low-Molecular-Weight Poly(lactic acid)s. Biomacromolecules, Vol. 5, No. 4, pp. 1181-1186 (2004).

(62) Hideto Tsuji, Kensaku Ikarash: In Vitro Hydrolysis of Poly(L-lactide) Crystalline Residues as Extended-Chain Crystallites: III. Effects of pH and Enzyme; Polymer Degradation and Stability, Vol. 85, No. 1, pp. 647-656 (2004).

(61) Hideto Tsuji, Kensaku Ikarash, Norio Fukuda: Poly(L-lactide): XII. Formation, Growth, and Morphology of Crystalline Residues as Extended-Chain Crystallites through Hydrolysis of Poly(L-lactide) Films, in Phosphate-Buffered Solution; Polymer Degradation and Stability, Vol. 84, No. 3, pp. 515-523 (2004).

(60) Hideto Tsuji, Kensaku Ikarash: In Vitro Hydrolysis of Poly(L-lactide) Crystalline Residues as Extended-Chain Crystallites: II. Effects of Hydrolysis Temperature; Biomacromolecules, Vol. 5, No. 3, pp.1021-1028 (2004).

(59) Hideto Tsuji, Kensaku Ikarash: In Vitro Hydrolysis of Poly(L-lactide) Crystalline Residues as Extended-Chain Crystallites: I. Long-Term Hydrolysis in Phosphate-Buffered Solution at 37℃; Biomaterials, Vol. 25, No. 24, pp. 5449-5455 (2004).

 

(2003)

(58) Mitsugu Todo, Nobuyuki Shinohara, Kazuo Arakawa, Hideto Tsuji:Effects of Hydrolysis in Fracture Behavior of Poly(L-lactide), Kobunshi Ronbunshu, Vol. 60, No. 11, p.644-651 (2003). [In Japanese except for Abstract, Figures, and Tables (English)]

(57) Hideto Tsuji, Ippei Fukui, Hiroyuki Daimon, Koichi Fujie: Poly(L-lactide): XI. Lactide Formation by Thermal Depolymerization of Poly(L-lactide) in a Closed System; Polymer Degradation and Stability, Vol. 81, No. 3, pp. 501-509 (2003).

(56) Hideto Tsuji, Kaori Suzuyoshi, Yasufumi Tezuka, Takuya Ishida: Environmental Degradation of Biodegradable Polyesters: 3. Effects of Alkali-Treatment on Biodegradation of Poly(e-caprolactone) and Poly[(R)-3-hydroxybutyrate) Films in Controlled Soil; Journal of Polymers and the Environment, Vol. 11, No. 2, pp. 57-65 (2003).

(55) Hideto Tsuji, Kaori Suzuyoshi: Environmental Degradation of Biodegradable Polyesters: 4. Effects of Pores and Surface Hydrophilicity on Biodegradation of Poly(e-caprolactone) and Poly[(R)-3-hydroxybutyrate)] Films in Controlled Seawater; Journal of Applied Polymers Science, Vol. 90, No. 2, pp. 587-593 (2003).

(54) Kosuke Tomita, Hideto Tsuji, Tomohiro Nakajima, Yumi Kikuchi, Kensaku Ikarashi, Noritoshi Ikeda: Degradation of poly(D-lactide) by a Thermophile; Polymer Degradation and Stability, Vol. 81, No.1, p.167-171 (2003).

(53) Hideto Tsuji, Takuya Ishida, Norio Fukuda: Surface Hydrophilicity and Enzymatic Hydrolyzability of Biodegradable Polyesters. 1. Effects of Alkaline Treatment; Polymer International, Vol. 52, No.5, pp. 843-852 (2003).

(52) Hideto Tsuji, Hiroyuki Daimon, Koichi Fujie: A New Strategy for Recycling and Preparation of Poly(L-lactic acid): Hydrolysis in the Melt; Biomacromolecules, Vol. 4, No.3, pp. 835-840 (2003).

(51) Hideto Tsuji, Ippei Fukui: Enhanced Thermal Stability of Poly(lactide)s in the Melt by Enantiomeric Polymer Blending; Polymer, Vol. 44, No.10, pp. 2891-2896 (2003).

(50) Hideto Tsuji, Takuya Ishida: Surface Hydrophilicity and Enzymatic Hydrolyzability of Biodegradable Polyesters. 2. Effects of Hydrophilic Polymer Coating; Macromolecular Bioscience, Vol. 3, No.1, pp. 51-59 (2003).

(49) Hideto Tsuji, Tamami Yamada, M. Suzuki, S. Itsuno: Blends of Aliphatic Polyesters: VII. Effects of Poly(L-lactide-co-e-caprolactone) on Morphology, Structure, Crystallization, and Physical Properties of Blends of Poly(L-lactide) and Poly(e-caprolactone); Polymer International, Vol. 52, No.2, pp. 269-275 (2003).

(48) Hideto Tsuji, Carlos Adriel Del Carpio: In Vitro Hydrolysis of Blends from Enantiomeric Poly(lactide)s. 3. Homo-Crystallized and Amorphous Blend Films; Biomacromolecules, Vol. 4, No.1, pp. 7-11 (2003).

(47) Hideto Tsuji, Takuya Ishida: Poly(L-lactide): X. Enhanced Surface Hydrophilicity and Chain-Scission Mechanisms of Poly(L-lactide) Film in Enzymatic, Alkaline, and Phosphate-Buffered Solutions, Journal of Applied Polymer Science, Vol. 87, No. 10, pp. 1628-1633 (2003).

(46) Hideto Tsuji: In Vitro Hydrolysis of Blends from Enantiomeric Poly(lactide)s. 4. Well-Homo-Crystallized Blend and Nonblended Films, Biomaterials, Vol. 24, No. 4, pp. 537-547 (2003).

(45) Hideto Tsuji, Tamami Yamada: Blends of Aliphatic Polyesters. VIII. Effects of Poly(L-lactide-co-e-caprolactone) on Enzymatic Hydrolysis of Poly(L-lactide), Poly(e-caprolactone), and Their Blend Films, Journal of Applied Polymer Science, Vol.87, No.3, pp. 412-419 (2003).

 

(2002)

(44) Norio Fukuda, Hideto Tsuji, Yasushi Ohnishi: Physical Properties and Enzymatic Hydrolysis of Poly(L-lactide)-CaCO3 Composites, Polymer Degradation and Stability, Vol. 78, No.1, p.119-127 (2002).

(43) Hideto Tsuji, Kazumasa Nakahara: Poly(L-lactide): IX. Hydrolysis in Acid Media; Journal of Applied Polymer Science, Vol. 86, No.1, pp. 186-194 (2002).

(42) Hideto Tsuji, Autocatalytic Hydrolysis of Amorphous-Made Polylactides: Effects of L-lactide Content, Tacticity, and Enantiomeric Polymer Blending; Polymer, Vol. 43, No.6, pp. 1789-1796 (2002).

(41) Hideto Tsuji, Kaori Suzuyoshi: Environmental Degradation of Biodegradable Polyesters: 2. Poly(e-caprolactone), Poly[(R)-3-hydroxybutyrate), and Poly(L-lactide) Films in Natural Dynamic Seawater; Polymer Degradation and Stability, Vol.75, No.2, pp. 357-363 (2002).

(40) Hideto Tsuji, Kaori Suzuyoshi: Environmental Degradation of Biodegradable Polyesters: 1. Poly(e-caprolactone), Poly[(R)-3-hydroxybutyrate), and Poly(L-lactide) Films in Controlled Static Seawater; Polymer Degradation and Stability, Vol.75, No.2, pp. 347-355 (2002).

 

(2001)

(39) Hideto Tsuji, Takeharu Ishizaka: Blends of Aliphatic Polyesters: VI. Lipase-Catalyzed Hydrolysis and Visualized Phase Structure of Biodegradable Blends from Poly(e-caprolactone) and Poly(L-lactide); International Journal of Biological Macromolecules, Vol. 29, No. 2, pp. 83-89 (2001).

(38) Hideto Tsuji, Kazumasa Nakahara, Kensaku Ikarashi: Poly(L-lactide): 8. High-Temperature Hydrolysis of Poly(L-lactide) Films with Different Crystallinities and Crystalline Thicknesses in Phosphate-Buffered Solution; Macromolecular Materials and Engineering, Vol.286, No.7, pp. 398-406 (2001).

(37) Hideto Tsuji, Hiroki Muramatsu: Blends of Aliphatic Polyesters. 4.Morpholgy,Swelling behavior, and Surface and Bulk Properties of Blends from Hydrophobic Poly(L-lactide) and Hydrophilic Poly(vinyl alcohol); Journal of Applied Polymer Science, Vol. 81, No.9, pp. 2151-2160 (2001).

(36) Hideto Tsuji, Shinya Miyauchi: Enzymatic Hydrolysis of Poly(lactide)s: Effects of Molecular Weight, L-lactide Content, and Enantiomeric and Diastereoisomeric Polymer Blending; Biomacromolecules, Vol. 2, No. 2, pp. 597-604 (2001).

(35) Hideto Tsuji, Masakazu Suzuki: In Vitro Hydrolysis of Blends from Enantiomeric Poly(lactide)s. 2. Well-stereocomplexed Fiber and Film, Sen'i Gakkaishi (繊維学会誌), Vol.57, No.6, pp. 198-202 (2001).

(34) Hideto Tsuji, Takeharu Ishizaka: Porous Biodegradable Polyesters: 3. Preparation of Porous Poly(ε-caprolactone) Films from Blends by Selective Enzymatic Removal of Poly(L-lactide); Macromolecular Bioscience, Vol.1, No.2, pp. 59-65 (2001).

(33) Hideto Tsuji, Takeharu Ishizaka: Porous Biodegradable Polyesters. 2.Physical Properties, Morphology, and Enzymatic and Alkaline Hydrolysis of Porous Poly(ε-caprolactone) Films; Journal of Applied Polymer Science, Vol.80, No.12, pp. 2281-2291 (2001).

(32) Hideto Tsuji, Shinya Miyauchi: Poly(L-lactide): 7. Enzymatic Hydrolysis of Free and Restricted Amorphous Regions in Poly(L-lactide) Films with Different Crystallinities and a Fixed Crystalline Thickness;Polymer, Vol.42, No. 9, pp. 4463-4467 (2001).

(31) Hideto Tsuji, Shinya Miyauchi: Poly(L-lactide). 6.Effects of Crystallinity on Enzymatic Hydrolysis of Poly(L-lactide) without Free Amorphous Region; Polymer Degradation and Stability, Vol.71, No.3, pp. 415-424 (2001).

(30) Hideto Tsuji, Hiroki Muramatsu: Blends of Aliphatic Polyesters. 5.Non-enzymatic and Enzymatic Hydrolysis of Blends from Hydrophobic Poly(L-lactide) and Hydrophilic Poly(vinyl alcohol) Polymer Degradation and Stability, Vol.71, No.3, pp. 403-413 (2001).

(29) Hideto Tsuji, Kimika Sumida: Poly(L-lactide). 5.Effects of Storage in Swelling Solvents on Physical Properties and Structure of Poly(L-lactide); Journal of Applied Polymer Science, Vol.79, No.9, pp. 1582-1589 (2001).

 

[Hideto Tsuji, Kazumasa Nakahara, Kensaku Ikarashi, Macromolecular Materials and Engineering, Vol.286, No.7 (2001), cover picture]

 

(1999-2000)

(28) J. Puiggali, Y. Ikada, H. Tsuji, L. Cartier, T. Okihara, B. Lotz: The Frustrated Structure of Poly(L-lactide); Polymer, Vol.41, No.25, pp. 8921-8930 (2000).

(27) L. Cartie, T. Okihara, Y. Ikada, H. Tsuji, J. Puiggali, B. Lotz: Epitaxial Crystallization and Crystalline Polymorphism of Polylactides; Polymer, Vol.41, No.25, p.8909-8919 (2000).

(26) Hideto Tsuji: In Vitro Hydrolysis of Blends from Enantiomeric Poly(lactide)s.1.Well-stereocomplexed blend and non-blended films; Polymer, Vol.41, No.10, pp. 3621-3630 (2000).

(25) Hideto Tsuji, Raymond Smith, William Bonfield, Yoshito Ikada:Porous Biodegradable Polyesters.1.Preparation of Porous Poly(L-lactide) Films by Extraction of Poly(ethylene oxide) from their blends; Journal of Applied Polymer Science, Vol.75, No.5, pp. 629-637 (2000).

(24) Hideto Tsuji, Akira Mizuno, Yoshito Ikada: Enhanced Crystallization of Poly(L-lactide-co-ε-caprolactone) during Storage at Room Temperature; Journal of Applied Polymer Science, Vol. 76, No.6, pp. 947-953 (2000).

(23) Hideto Tsuji, Akira Mizuno, Yoshito Ikada: Properties and Morphology of Poly(L-lactide). 3.Effects of Crystallinity on Long-Term In Vitro Hydrolysis of Poly(L-lactide) Film in Phosphate-Buffered Solution; Journal of Applied Polymer Science, Vol.77, No.7, pp. 1452-1464 (2000).

(22) Hideto Tsuji, Yoshito Ikada: Properties and Morphology of Poly(L-lactide). 4.Effects of Structural Parameters on Long-Term In Vitro Hydrolysis of Poly(L-lactide) in Phosphate-Buffered Solution; Polymer Degradation and Stability, Vol.67, No.1, pp. 179-189 (2000).

(21) Hideto Tsuji, Yoshito Ikada: Stereocomplex Formation between Enantiomeric Poly(lactic acid)s. 11. Mechanical Properties and Morphology of Solution-Cast Films; Polymer, Vol.40, No.24, pp. 6699-6708(1999).

 

(1996-1998)

(20) Hideto Tsuji, Yoshito Ikada: Properties and Morphology of Poly(L-lactide). II. Hydrolysis in Alkaline Solution; Journal of Polymer Science: Part A: Polymer Chemistry, Vol.36, pp. 59-66(1998).

(19) Hideto Tsuji, Yoshito Ikada: Blends of Aliphatic Polyesters. II.Hydrolysis of Solution-Cast Blends from Poly(L-lactide) and Poly(e-caprolactone) in Phosphate-Buffered Solution; Journal of Applied Polymer Science, Vol.67, pp. 405-415(1998).

(18) Hideto Tsuji, Akira Mizuno, Yoshito Ikada: Blends of Aliphatic Polyesters. III.Biodegradation of Solution-Cast Blends from Poly(L-lactide) and Poly(e-caprolactone); Journal of Applied Polymer Science, Vol.70, pp. 2259-2268 (1998).

(17) Hideto Tsuji, Yoshito Ikada: Blends of Crystalline and Amorphous Poly(lactide). III. Hydrolysis of Solution-cast Blend Films; Journal of Applied Polymer Science, Vol.63, pp. 855-863 (1997).  

(16) Hideto Tsuji, Yoshito Ikada: Blends of Isotactic and Atactic Poly(lactide)s. 2. Molecular-weight Effects of Atactic Component on Crystallization and Morphology of Equimolar Blends from the Melt; Polymer, Vol. 37, No. 4, pp. 595-602 (1996).

(15) Hideto Tsuji, Yoshito Ikada: Blends of Aliphatic Polyesters. I. Physical Properties and Morphologies of Solution-Cast Blends from Poly(DL-lactide) and Poly(e-caprolactone); Journal of Applied Polymer Science, Vol.60, No.13, pp. 2367-2375 (1996).  

(14) Hideto Tsuji, Yoshito Ikada: Crystallization from the Melt of Poly(Lactide)s with Different Optical Properties and Their Blends; Macromolecular Chemistry and Physics, Vol.197, No.10, pp. 3483-3499 (1996).

 

(1987-1995)

(13) Hideto Tsuji, Yoshito Ikada: Properties and Morphologies of Poly(L-lactide): 1. Annealing Effects on Properties and Morphologies of Poly(L-lactide); Polymer, Vol. 36, No.14, pp. 2709-2716 (1995).

(12) Hideto Tsuji, Yoshito Ikada: Blends of Isotactic and Atactic Poly(lactide)s. I. Effects of Mixing Ratio of Isomers on Crystallization of Blends from Melt; Journal of Applied Polymer Science, Vol.58, No.10, pp. 1793-1802 (1995). 

(11) Hideto Tsuji, Yoshito Ikada: Stereocomplex Formation between Enantiomeric Poly(lactic acid)s. X. Binary Blends from Poly(D-lactide-co-glycolide) and Poly(L-lactide-co-glycolide); Journal of Applied Polymer Science, Vol.53, No.7, pp. 1061-1071 (1994).

(10) Hideto Tsuji, Yoshito Ikada, Suong-Hyu Hyon, Yoshiharu Kimura, Toshio Kitao:S tereocomplex Formation between Enantiomeric Poly(lactic acid)s. VIII. Complex Fibers Spun from Mixed Solution of Poly(D-lactic acid) and Poly(L-lactic acid); Journal of Applied Polymer Science, Vol.51, No.2, pp. 337-344 (1994).

(9) Hideto Tsuji, Yoshito Ikada: Stereocomplex Formation between Enantiomeric Poly(lactic acid)s. 9. Stereocomplexation from the Melt; Macromolecules, Vol. 26, No.25, pp. 6918-6926 (1993).

(8) Hideto Tsuji, Yoshito Ikada: Stereocomplex Formation between Enantiomeric Poly(lactic acid)s. 6. Binary Blends from Copolymers; Macromolecules, Vol. 25, No.21, pp. 5719-5723 (1992).

(7) Hideto Tsuji, Fumitaka Horii, Masaru Nakagawa, Yoshito Ikada, Hisashi Odani, Ryozo Kitamaru: Stereocomplex Formation between Enantiomeric Poly(lactic acid)s. 7. Phase Structure of the Stereocomplex Crystallized from a Dilute Acetonitrile Solution As Studied by High-Resolution Solid-State 13C NMR Spectroscopy; Macromolecules, Vol. 25, No.16, pp. 4114-4118 (1992).

(6) Hideto Tsuji, Suong-Hyu Hyon, Yoshito Ikada:Stereocomplex Formation between Enantiomeric Poly(lactic acid)s. 5. Calorimetric and Morphological Studies in the Streocomplex Fromed in Acetonitrile Solution; Macromolecules, Vol. 25, No.11, pp. 2940-2946 (1992).

(5) Hideto Tsuji, Suong-Hyu Hyon, Yoshito Ikada: Stereocomplex Formation between Enantiomeric Poly(lactic acid)s. 4. Differential Scanning Calorimetric Studies on Precipitates from Mixed Solutions of Poly(D-lactic acid) and Poly(L-lactic acid); Macromolecules, Vol. 24, No.20, pp. 5657-5662 (1991).

(4) Hideto Tsuji, Suong-Hyu Hyon, Yoshito Ikada: Stereocomplex Formation between Enantiomeric Poly(lactic acid)s. 3. Calorimetric Studies on Blend Films Cast from Dilute Solutions; Macromolecules, Vol. 24, No.20, pp. 5651-5656 (1991).

(3) Hideto Tsuji, Fumitaka Horii, Suong-Hyu Hyon, Y. Ikada: Stereocomplex Formation between Enantiomeric Poly(lactic acid)s. 2. Stereocomplex Formed in Concentrated Solutions; Macromolecules, Vol. 24, No.10, pp. 2719-2724 (1991).

(2) Takumi Okihara, Masaki Tsuji, Akiyoshi Kawaguchi, Ken-ichi Katayama, Hideto Tsuji, Suong-Hyu Hyon, Yoshito Ikada:Crystal Structure of Stereocomplex of Poly(L-lactide) and Poly(D-lactide); Journal of Macromolecular Science-Physics, Vol.B30, No.1&2, pp. 119-140 (1991).

(1) Yoshito Ikada, Khosrow Jamshidi, Hideto Tsuji, Suong-Hyu Hyon: Stereocomplex Formation between Enantiomeric Polylactides; Macromolecules, Vol. 20, No.4, pp. 904-906 (1987).

 

特許

(12) 発明者:辻 秀人 、成田淳一(東セロ株式会社)、出願人:国立大学法人 豊橋技術科学大学学長 西永 頌、東セロ株式会社、富永紘一、特願2007-179056、「生分解性ポリエステル組成物」.

(11) 発明者:辻 秀人、水野 彰、高島和則、桂 進司(群馬大学)、中野道彦、橋本 誠、出願人:国立大学法人 豊橋技術科学大学学長 西永 頌、特願2006-301186、「電界印加によるステレオコンプレックス化ポリ乳酸材料の作製方法」.

(10) 発明者:辻 秀人、滝川浩史、田中三郎、川島善夫、出願人:国立大学法人 豊橋技術科学大学学長 西永 頌、特願2006-219614、「導電性ポリ乳酸組成物].

(9) 発明者:佐伯孝、大門裕之、辻 秀人、藤江幸一、中島実(帝人ファイバー)、石原健一(帝人ファイバー)、出願人:国立大学法人 豊橋技術科学大学学長 西永 頌、帝人ファイバー株式会社、特開2006-137892(特願2004-330154)、「ポリ乳酸廃棄物の再生方法」.

(8) 発明者:佐伯孝、大門裕之、辻 秀人、藤江幸一、堀内裕志(帝人ファイバー)、石原健一(帝人ファイバー)、出願人:国立大学法人 豊橋技術科学大学学長 西永 頌、帝人ファイバー株式会社、特開2005-330211(特願2004-149151)、「生分解性ポリエステルのモノマー化方法、及び生分解性ポリエステルの処理装置」.

(7) 発明者:辻 秀人、川島善夫、滝川浩史、田中三郎、出願人:国立大学法人 豊橋技術科学大学学長 西永 頌、特開2005-290288(特願2004-109842)、「カーボン系ナノ物質を添加した生分解性ポリエステル」.

(6) 発明者:辻 秀人、藤江幸一、大門裕之、出願人:国立大学法人 豊橋技術科学大学学長 西永 頌、特開2005-298401(特願2004-116653)、「生分解性ポリエステルのモノマー化方法」.

(5) 発明者:辻 秀人、藤江幸一、大門裕之、出願人:国立大学法人 豊橋技術科学大学学長 西永 頌、特開2005-264000(特願2004-079317)、「生分解性の疎水性ポリエステルの製法方法」.

(4) 発明者:福田徳生(愛知県産業技術研究所)、大西保志(愛知県産業技術研究所)、辻 秀人、山田和信(ユニチカ株式会社中央研究所)、出願人:神田真秋(愛知県知事)、辻 秀人、ユニチカ株式会社、特開2004-75727(特願2002-234239)、「生分解速度の制御されたポリ乳酸系樹脂組成物およびその成形体」.

(3) 発明者:辻 秀人、藤江幸一、大門裕之、出願人:科学技術振興事業団(JST)、特開2003-313283(特願2002-123449)、「ポリエステルの製法」.

(2) 発明者:藤江幸一、辻 秀人、大門裕之、出願人:財団法人名古屋市産業科学研究所、特開2003-300927(特願2002-109918)、「生分解性ポリエステルのモノマー化方法等」.

(1) 発明者:辻 秀人、出願人:科学技術振興事業団(JST)、特開2003-277534(特願2002-090043)、「生分解性ポリエステル樹脂成形物およびその製造方法」.

 

 

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